β,γ-Unsaturated α-aminophosphonates:: synthesis and reactivity

被引：26

作者：

Atmani, A

Combret, JC

Malhiac, C

Mulengi, JK

机构：

[1] Univ Rouen, Lab Heterochim Organ, F-76134 Mt St Aignan, France

[2] Univ Tlemcen, Inst Chim, Synth Organ Lab, Tlemcen 13000, Algeria

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 32期

关键词：

D O I：

10.1016/S0040-4039(00)00922-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Vinylogous iminium stilts from gamma-aminoenamines react with triethylphosphite to afford amino phosphonates in moderate to good yields. The latter are easily converted to alpha-substituted aminoallylphosphonates that can yield alpha-substituted aminoallylphosphonates on reaction with butyllitium and a series of electrophiles. (C) 2000 Elsevier Science Ltd, All rights reserved.

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页码：6045 / 6048

页数：4

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