Solid-state nuclear magnetic resonance: A valuable tool to explore organic-inorganic interfaces in silica-based hybrid materials

被引:43
作者
Babonneau, Florence [1 ]
Baccile, Nilci [1 ]
Laurent, Guillaume [1 ]
Maquet, Jocelyne [1 ]
Azais, Thierry [1 ]
Gervais, Christel [1 ]
Bonhomme, Christian [1 ]
机构
[1] Univ Paris 06, CNRS, Lab Chim Matiere Condensee Paris, Coll France, F-75231 Paris 05, France
关键词
Solid-state NMR; Silica; Hybrids; Interfaces; NMR CHARACTERIZATION; MESOPOROUS SILICAS; AMORPHOUS SILICA; SI-29; NMR; AB-INITIO; COUPLINGS; SURFACE; ORGANOALKOXYSILANES; POLYMERIZATION; SPECTROSCOPY;
D O I
10.1016/j.crci.2009.08.001
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This article illustrates the suitability of solid-state NMR for the in-depth description of organic-inorganic interfaces in silica-based hybrid materials. The examples were selected as representatives of some of the most studied families of hybrid materials, such as functionalized silica particles and templated mesostructured silica To cite this article: F. Babonneau et al., C. R. Chimie 13 (2010). (C) 2009 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.
引用
收藏
页码:58 / 68
页数:11
相关论文
共 50 条
[1]   Benzoylthiourea-modified mesoporous silica for mercury(II) removal [J].
Antochshuk, V ;
Olkhovyk, O ;
Jaroniec, M ;
Park, IS ;
Ryoo, R .
LANGMUIR, 2003, 19 (07) :3031-3034
[2]   Solid-state NMR study of ibuprofen confined in MCM-41 material [J].
Azais, Thierry ;
Tourne-Peteilh, Corine ;
Aussenac, Fabien ;
Baccile, Niki ;
Coelho, Cristina ;
Devoisselle, Jean-Marie ;
Babonneau, Florence .
CHEMISTRY OF MATERIALS, 2006, 18 (26) :6382-6390
[3]   Solid-state NMR characterization of drug-model molecules encapsulated in MCM-41 silica [J].
Azais, Thierry ;
Hartmeyer, Geoffrey ;
Quignard, Sandrine ;
Laurent, Guillaume ;
Tourne-Peteilh, Corine ;
Devoisselle, Jean-Marie ;
Babonneau, Florence .
PURE AND APPLIED CHEMISTRY, 2009, 81 (08) :1345-1355
[4]   Solid state NMR characterisation of encapsulated molecules in mesoporous silica [J].
Babonneau, F ;
Yeung, L ;
Steunou, N ;
Gervais, C ;
Ramila, A ;
Vallet-Regi, M .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2004, 31 (1-3) :219-223
[5]  
BABONNEAU F, 1992, MATER RES SOC SYMP P, V271, P237, DOI 10.1557/PROC-271-237
[6]   HYBRID SILOXANE-OXIDE MATERIALS VIA SOL-GEL PROCESSING - STRUCTURAL CHARACTERIZATION [J].
BABONNEAU, F .
POLYHEDRON, 1994, 13 (08) :1123-1130
[7]   Investigation by 1H-29 SiHETCOR NMR experiments of surfactant/silica interfaces in mesostructured materials with ordered porosity [J].
Baccile, N ;
Maquet, J ;
Babonneau, F .
COMPTES RENDUS CHIMIE, 2006, 9 (3-4) :478-484
[8]   Organo-modified mesoporous silicas for organic pollutant removal in water: Solid-state NMR study of the organic/silica interactions [J].
Baccile, Niki ;
Babonneau, Florence .
MICROPOROUS AND MESOPOROUS MATERIALS, 2008, 110 (2-3) :534-542
[9]   Solid-state NMR characterization of the surfactant-silica interface in templated silicas: Acidic versus basic conditions [J].
Baccile, Niki ;
Laurent, Guillaume ;
Bonhomme, Christian ;
Innocenzi, Plinio ;
Babonneau, Florence .
CHEMISTRY OF MATERIALS, 2007, 19 (06) :1343-1354
[10]   CORRELATIONS BETWEEN PROTON CHEMICAL-SHIFT TENSORS, DEUTERIUM QUADRUPOLE COUPLINGS, AND BOND DISTANCES FOR HYDROGEN-BONDS IN SOLIDS [J].
BERGLUND, B ;
VAUGHAN, RW .
JOURNAL OF CHEMICAL PHYSICS, 1980, 73 (05) :2037-2043