Synthesis of Bimetallic Uranium and Neptunium Complexes of a Binucleating Macrocycle and Determination of the Solid-State Structure by Magnetic Analysis

被引：38

作者：

Arnold, Polly L. ^{[1
]}

Potter , Natalie A. ^{[1
]}

Magnani, Nicola ^{[2
]}

Apostolidis, Christos ^{[2
]}

Griveau, Jean-Christophe ^{[2
]}

Colineau, Eric ^{[2
]}

Morgenstern, Alfred ^{[2
]}

Caciuffo, Roberto ^{[2
]}

Love, Jason B. ^{[1
]}

机构：

[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

[2] European Commiss, Joint Res Ctr, Inst Transuranium Elements, D-76125 Karlsruhe, Germany

来源：

INORGANIC CHEMISTRY | 2010年 / 49卷 / 12期

关键词：

SINGLE-MOLECULE MAGNETS; SCHIFF-BASE; ACTINIDE; LANTHANIDE; OXO;

D O I：

10.1021/ic100374j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Syntheses of the bimetallic uranium(III) and neptunium(III) complexes [(Ul)(2)(L)], [(Npl)(2)(L)], and [{U(BH4)}(2)(L)] of the Schiff-base pyrrole macrocycles L are described. In the absence of single-crystal, structural data, fitting of the variable-temperature solid-state magnetic data allows the prediction of polymeric structures for these compounds in the solid state.

引用

页码：5341 / 5343

页数：3

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