Selective oxo functionalization of the uranyl ion with 3d metal cations

被引：128

作者：

Arnold, Polly L. ^{[1
]}

Patel, Dipti ^{[1
]}

Blake, Alexander J. ^{[1
]}

Wilson, Claire ^{[1
]}

Love, Jason B. ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 30期

关键词：

D O I：

10.1021/ja0634167

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The linear uranyl dication [UO2]2+ can be bound in one of two coordination sites in the ditopic Pacman-shaped pyrrolic macrocyle H4L. Incorporation of Mn2+, Fe2+, or Co2+ cations in the second donor compartment affords the first uranyl complexes with a transition-metal-functionalized oxo group. Copyright © 2006 American Chemical Society.

引用

页码：9610 / 9611

页数：2

共 29 条

[1] MULTINUCLEAR NMR, RAMAN, EXAFS, AND X-RAY-DIFFRACTION STUDIES OF URANYL CARBONATE COMPLEXES IN NEAR-NEUTRAL AQUEOUS-SOLUTION - X-RAY STRUCTURE OF [C(NH2)(3)](6)[(UO2)(3)(CO3)(6)]CENTER-DOT-6.5H(2)O [J].

ALLEN, PG ;

BUCHER, JJ ;

CLARK, DL ;

EDELSTEIN, NM ;

EKBERG, SA ;

GOHDES, JW ;

HUDSON, EA ;

KALTSOYANNIS, N ;

LUKENS, WW ;

NEU, MP ;

PALMER, PD ;

REICH, T ;

SHUH, DK ;

TAIT, CD ;

ZWICK, BD .

INORGANIC CHEMISTRY, 1995, 34 (19) :4797-4807

[2] Uranyl complexation by a schiff-base, polypyrrolic macrocycle [J].

Arnold, PL ;

Blake, AJ ;

Wilson, C ;

Love, JB .

INORGANIC CHEMISTRY, 2004, 43 (26) :8206-8208

[3]

BENETOLLO G, 1995, J ALLOY COMPD, V225, P400

[4] A trigonal bipyramidal uranyl amido complex:: Synthesis and structural characterization of [Na(THF)2] [UO2(N(SiMe3)2)3] [J].

Burns, CJ ;

Clark, DL ;

Donohoe, RJ ;

Duval, PB ;

Scott, BL ;

Tait, CD .

INORGANIC CHEMISTRY, 2000, 39 (24) :5464-5468

[5] Coordination trends in alkali metal crown ether uranyl halide complexes:: The series [A(Crown)]2[UO2X4] where A = Li, Na, K and X = Cl, Br [J].

Danis, JA ;

Lin, MR ;

Scott, BL ;

Eichhorn, BW ;

Runde, WH .

INORGANIC CHEMISTRY, 2001, 40 (14) :3389-3394

[6] Covalency in the uranyl ion: A polarized x-ray spectroscopic study [J].

Denning, RG ;

Green, JC ;

Hutchings, TE ;

Dallera, C ;

Tagliaferri, A ;

Giarda, K ;

Brookes, NB ;

Braicovich, L .

JOURNAL OF CHEMICAL PHYSICS, 2002, 117 (17) :8008-8020

[7] STEREOGNOSTIC COORDINATION CHEMISTRY .1. THE DESIGN AND SYNTHESIS OF CHELATORS FOR THE URANYL-ION [J].

FRANCZYK, TS ;

CZERWINSKI, KR ;

RAYMOND, KN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (21) :8138-8146

[8] Macrocyclic diiminodipyrromethane complexes:: structural analogues of Pac-Man porphyrins [J].

Givaja, G ;

Blake, AJ ;

Wilson, C ;

Schröder, M ;

Love, JB .

CHEMICAL COMMUNICATIONS, 2003, (19) :2508-2509

[9]

GIVAJA G, 2006, UNPUB

[10] Rational design of sequestering agents for plutonium and other actinides [J].

Gorden, AEV ;

Xu, JD ;

Raymond, KN ;

Durbin, P .

CHEMICAL REVIEWS, 2003, 103 (11) :4207-4282

← 1 2 3 →