A catalytic deracemisation of alcohols

被引:36
作者
Adair, Gareth R. A. [1 ]
Williams, Jonathan M. J. [1 ]
机构
[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
关键词
D O I
10.1039/b704956k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Racemic alcohols have been converted into enantiomerically enriched alcohols with up to 99% ee in a one-pot oxidation/reduction procedure.
引用
收藏
页码:2608 / 2609
页数:2
相关论文
共 17 条
[1]   A novel ruthenium catalysed deracemisation of alcohols [J].
Adair, GRA ;
Williams, JMJ .
CHEMICAL COMMUNICATIONS, 2005, (44) :5578-5579
[2]   THE OXIDATION POTENTIALS OF ALDEHYDES AND KETONES [J].
ADKINS, H ;
ELOFSON, RM ;
ROSSOW, AG ;
ROBINSON, CC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1949, 71 (11) :3622-3629
[3]   Ruthenium(II)-catalyzed Oppenauer-type oxidation of secondary alcohols [J].
Almeida, MLS ;
Beller, M ;
Wang, GZ ;
Backvall, JE .
CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (12) :1533-1536
[4]   A catalyst for efficient and highly enantioselective hydrogenation of aromatic, heteroaromatic, and α,β-unsaturated ketones [J].
Burk, MJ ;
Hems, W ;
Herzberg, D ;
Malan, C ;
Zanotti-Gerosa, A .
ORGANIC LETTERS, 2000, 2 (26) :4173-4176
[5]   Catalytic dehalogenation of aryl chlorides mediated by ruthenium(II) phosphine complexes [J].
Cucullu, ME ;
Nolan, SP ;
Belderrain, TR ;
Grubbs, RH .
ORGANOMETALLICS, 1999, 18 (07) :1299-1304
[6]   Synthesis and molecular modeling studies of SYNPHOS®, a new, efficient diphosphane ligand for ruthenium-catalyzed asymmetric hydrogenation [J].
de Paule, SD ;
Jeulin, S ;
Ratovelomanana-Vidal, V ;
Genêt, JP ;
Champion, N ;
Dellis, P .
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2003, 2003 (10) :1931-1941
[7]   Asymmetric transfer hydrogenation: chiral ligands and applications [J].
Gladiali, S ;
Alberico, E .
CHEMICAL SOCIETY REVIEWS, 2006, 35 (03) :226-236
[8]   From a racemate to a single enantiomer: Deracemization by stereoinversion [J].
Gruber, Christian C. ;
Lavandera, Ivan ;
Faber, Kurt ;
Kroutil, Wolfgang .
ADVANCED SYNTHESIS & CATALYSIS, 2006, 348 (14) :1789-1805
[9]  
Kitamura M., 1993, ORG SYNTH, V71, P1
[10]   SYNTHESIS OF NEW CATIONIC BINAP-RUTHENIUM(II) COMPLEXES AND THEIR USE IN ASYMMETRIC HYDROGENATION [BINAP = 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL] [J].
MASHIMA, K ;
KUSANO, KH ;
OHTA, T ;
NOYORI, R ;
TAKAYA, H .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (17) :1208-1210