Metal-Free Frustrated Lewis Pair Catalyzed 1,4-Hydrogenation of Conjugated Metallocene Dienamines

被引：69

作者：

Schwendemann, Sina ^{[1
]}

Tumay, Tuelay Ash ^{[1
]}

Axenov, Kirill V. ^{[1
]}

Peuser, Ilona ^{[1
]}

Kehr, Gerald ^{[1
]}

Froehlich, Roland ^{[1
]}

Erker, Gerhard ^{[1
]}

机构：

[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

来源：

ORGANOMETALLICS | 2010年 / 29卷 / 05期

关键词：

HETEROLYTIC DIHYDROGEN ACTIVATION; FREE HYDROGEN ACTIVATION; H-2; ACTIVATION; REACTIVITY; FACILE; BORANE; B(C6F5)(3); CHELATE; IMINES; COPOLYMERIZATION;

D O I：

10.1021/om900963p

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Frustrated Lewis pairs, highly active in heterolytic dihydrogen splitting, were used as active and very selective hydrogenation catalysts for organometallic substrates. Conjugated dienamines fixed at the ferrocene framework and at the zirconocene nucleus were selectively 1,4-hydrogenated under catalytic conditions at ambient temperature.

引用

页码：1067 / 1069

页数：3

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