Di- and polymetallic heteroatom stabilized (Fischer) metal carbene complexes

被引:243
作者
Sierra, MA [1 ]
机构
[1] Univ Complutense, Fac Quim, Dept Quim Organ 1, E-28040 Madrid, Spain
关键词
D O I
10.1021/cr9804137
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Heteroatom stabilized (Fischer) metal carbene complex was the starting point for the rapid development of the synthesis of organometallic compounds. The different aspects of the chemistry of Fisher carbenes and their synthetic applications are reviewed. Synthesis of Fisher carbenes by different processes and their reactivity in benzannulation, Pauson-Khand and other reactions are reviewed.
引用
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页码:3591 / 3637
页数:47
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