Non-planar structures of Et3N and Pri3 N:: a contradiction between the x-ray, and NMR and electron diffraction data for Pri3N

被引：35

作者：

Boese, R

Bläser, D

Antipin, MY

Chaplinski, V

de Meijere, A

机构：

[1] Univ Essen Gesamthsch, Inst Anorgan Chem, D-45117 Essen, Germany

[2] Russian Acad Sci, Inst Organoelement Cpds, Moscow 117813, Russia

[3] Univ Gottingen, Inst Organ Chem, D-37077 Gottingen, Germany

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 07期

关键词：

D O I：

10.1039/a708399h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structures of Et3N and (Pr3N)-N-i were determined by X-ray analysis using the in situ crystallization technique for single crystal growth on the diffractometer; both have a pyramidal configuration of the nitrogen atom, even (Pr3N)-N-i, which was considered to be planar in accord with electron diffraction and NMR data.

引用

页码：781 / 782

页数：2

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[21] UBER HOCHVERZWEIGTE ALIPHATISCHE VERBINDUNGEN .4. ERGIEBIGERE SYNTHESEN DES TRIISOPROPYLAMINS [J].