Formation and spectroscopic characterization of the peroxoFeIII-CuII complex.: A modeling reaction of the heme-Cu site in cytochrome c oxidase

被引：42

作者：

Sasaki, T ^{[1
]}

Nakamura, N ^{[1
]}

Naruta, Y ^{[1
]}

机构：

[1] Kyushu Univ, Inst Fundamental Res Organ Chem, Fukuoka 812, Japan

来源：

CHEMISTRY LETTERS | 1998年 / 04期

关键词：

D O I：

10.1246/cl.1998.351

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Formation of a unique peroxo complex (FeTPP)-T-II(O-2)-Cu(I)TPA 2 was observed in the oxygenated reaction of Fe pi TPP-Cu(I)TPA 1 with O-2 at ambient temperature. This complex was characterized by electronic absorption, ESI-MS, resonance Raman, and ESR spectroscopies.

引用

页码：351 / 352

页数：2

共 24 条

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