Graphene-silica composite thin films as transparent conductors

被引:773
作者
Watcharotone, Supinda
Dikin, Dmitriy A.
Stankovich, Sasha
Piner, Richard
Jung, Inhwa
Dommett, Geoffrey H. B.
Evmenenko, Guennadi
Wu, Shang-En
Chen, Shu-Fang
Liu, Chuan-Pu
Nguyen, SonBinh T.
Ruoff, Rodney S. [1 ]
机构
[1] Northwestern Univ, Dept Mech Engn, Evanston, IL 60208 USA
[2] Northwestern Univ, Dept Phys & Astron, Evanston, IL 60208 USA
[3] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
[4] Natl Cheng Kung Univ, Dept Mat Sci & Engn, Tainan 701, Taiwan
关键词
D O I
10.1021/nl070477+
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Transparent and electrically conductive composite silica films were fabricated on glass and hydrophilic SiOx/silicon substrates by incorporation of individual graphene oxide sheets into silica sols followed by spin-coating, chemical reduction, and thermal curing. The resulting films were characterized by SEM, AFM, TEM, low-angle X-ray reflectivity, XPS, UV-vis spectroscopy, and electrical conductivity measurements. The electrical conductivity of the films compared favorably to those of composite thin films of carbon nanotubes in silica.
引用
收藏
页码:1888 / 1892
页数:5
相关论文
共 49 条
[11]   Nanomechanical and nanotribological properties of carbon based films [J].
Charitidis, C ;
Logothetidis, S .
THIN SOLID FILMS, 2005, 482 (1-2) :120-125
[12]   Specular x-ray reflectivity study of ordering in self-assembled organic and hybrid organic-inorganic electro-optic multilayer films [J].
Evmenenko, G ;
van der Boom, ME ;
Kmetko, J ;
Dugan, SW ;
Marks, TJ ;
Dutta, P .
JOURNAL OF CHEMICAL PHYSICS, 2001, 115 (14) :6722-6727
[13]   Heat treatment and bending of low-E glass [J].
Finley, JJ .
THIN SOLID FILMS, 1999, 351 (1-2) :264-273
[14]   Transparent conductive indium tin oxide film fabricated by dip-coating technique from colloid precursor [J].
Gan, Yong ;
Liu, Jiaxiang ;
Zeng, Shengnan .
SURFACE & COATINGS TECHNOLOGY, 2006, 201 (1-2) :25-29
[15]   Sol-gel-derived ceramic-carbon nanotube nanocomposite electrodes: Tunable electrode dimension and potential electrochemical applications [J].
Gong, KP ;
Zhang, MN ;
Yan, YM ;
Su, L ;
Mao, LQ ;
Xiong, ZX ;
Chen, Y .
ANALYTICAL CHEMISTRY, 2004, 76 (21) :6500-6505
[16]   Transparent and conducting ITO films:: new developments and applications [J].
Granqvist, CG ;
Hultåker, A .
THIN SOLID FILMS, 2002, 411 (01) :1-5
[17]   Carbon nanotube films for transparent and plastic electronics [J].
Gruner, G. .
JOURNAL OF MATERIALS CHEMISTRY, 2006, 16 (35) :3533-3539
[18]   PREPARATION OF GRAPHITIC OXIDE [J].
HUMMERS, WS ;
OFFEMAN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339
[19]   Transparent conductive ITO thin films through the sol-gel process using metal salts [J].
Kim, SS ;
Choi, SY ;
Park, CG ;
Jin, HW .
THIN SOLID FILMS, 1999, 347 (1-2) :155-160
[20]   Effect of test atmosphere on the tribological behaviour of the non-hydrogenated diamond-like carbon coatings against 319 aluminum alloy and tungsten carbide [J].
Konca, E ;
Cheng, YT ;
Weiner, AM ;
Dasch, JM ;
Alpas, AT .
SURFACE & COATINGS TECHNOLOGY, 2005, 200 (5-6) :1783-1791