Asymmetric synthesis of 1-alkynylcyclopropane-1-carboxylates

被引：43

作者：

Davies, HML ^{[1
]}

Boebel, TA ^{[1
]}

机构：

[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 43期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(00)01453-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Dirhodium tetrakis(S-(N-dodecylbenzenesulfonyl)prolinate)(Rh2S-DOSP4) catalyzed decomposition of methyl alkynyldiazoacetates in the presence of alkenes results in highly diastereoselective and enantioselective cyclopropanations. (C) 2000 Published by Elsevier Science Ltd.

引用

页码：8189 / 8192

页数：4

共 15 条

[1]

Davies H. M. L., 1997, ALDRICHIM ACTA, V30, P107

[2]

Davies H.M. L., 1991, ORG SYNTH, V70, P93

[3] Asymmetric cyclopropanations by rhodium(II) N-(arylsulfonyl)prolinate catalyzed decomposition of vinyldiazomethanes in the presence of alkenes. Practical enantioselective synthesis of the four stereoisomers of 2-phenylcyclopropan-1-amino acid [J].