Two new bis-β-diketones as ligands for novel systems in supramolecular chemistry

被引：20

作者：

Aromí, G ^{[1
]}

Gamez, P ^{[1
]}

Berzal, PC ^{[1
]}

Driessen, WL ^{[1
]}

Reedijk, J ^{[1
]}

机构：

[1] Leiden Univ, Inst Chem, Gorlaeus Labs, NL-2300 RA Leiden, Netherlands

来源：

SYNTHETIC COMMUNICATIONS | 2003年 / 33卷 / 01期

关键词：

Claisen condensation; O-donor ligand; polynucleating ligand;

D O I：

10.1081/SCC-120015554

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Claisen condensations of 1,3-diacetyl-2-hydroxy-5-methylbenzene with esters gave two new outstanding tetraketone ligands. The optimized procedure was developed into a multi-grams scale preparation of 1,3-bis-(3-oxo-3-phenyl-propionyl)-2-hydroxy-5-methylbenzene.

引用

页码：11 / 18

页数：8

共 19 条

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