A tightly coupled bis(zinc(II) phthalocyanine)-perylenediimide ensemble to yield long-lived radical ion pair states

被引：126

作者：

Jimenez, Angel J.

Spaenig, Fabian

Rodriguez-Morgade, M. Salome

Ohkubo, Kei

Fukuzumi, Shunichi

Guldi, Dirk M.

Torres, Tomas

机构：

[1] Univ Autonoma Madrid, Dept Quim Organ, E-28049 Madrid, Spain

[2] Univ Erlangen Nurnberg, Inst Phys Chem, D-91058 Erlangen, Germany

[3] Osaka Univ, Grad Sch Engn, Dept Mat & Life Sci, Div Adv Sci & Biotechnol, Suita, Osaka 5650871, Japan

来源：

ORGANIC LETTERS | 2007年 / 9卷 / 13期

关键词：

D O I：

10.1021/ol0707968

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A conjugated donor-acceptor array composed of two phthalocyanines connected to the bay region of a perylenediimide is assembled by using palladium chemistry. Excitation of the phthalocyanine produces a nanosecond lived charge-separated state.

引用

页码：2481 / 2484

页数：4

共 36 条

[1] An organic photoelectrode working in the water phase: Visible-light-induced dioxygen evolution by a perylene derivative/cobalt phthalocyanine bilayer [J].

Abe, T ;

Nagai, K ;

Kabutomori, S ;

Kaneko, M ;

Tajiri, A ;

Noritnatsit, T .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (17) :2778-2781

[2]

[Anonymous], 1993, The Photosynthetic Reaction Center

[3]

BALZAMI V, 2001, ELECTRON TRANSFER CH

[4]

BLANKENSHIP RE, 2002, MOL MECHANSIMS PHOTO

[5]

Bohm A., 1997, Ger. Pat. Appl, Patent No. [DE19547209A1, 19547209, DE 19547209 A1]

[6]

Bohm A., 1997, CHEM ABSTR, Patent No. DE19547209A1

[7] Oligothiophene-functionalized perylene bisimide system: Synthesis, characterization, and electrochemical polymerization properties [J].

Chen, SY ;

Liu, YQ ;

Qiu, WF ;

Sun, X ;

Ma, YQ ;

Zhu, DB .

CHEMISTRY OF MATERIALS, 2005, 17 (08) :2208-2215

[8] Donor-acceptor phthalocyanine nanoaggregates [J].

de la Escosura, A ;

Martínez-Díaz, MV ;

Thordarson, P ;

Rowan, AE ;

Nolte, RJM ;

Torres, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (40) :12300-12308

[9] Role of structural factors in the nonlinear optical properties of phthalocyanines and related compounds [J].

de la Torre, G ;

Váquez, P ;

Agulló-López, F ;

Torres, T .

CHEMICAL REVIEWS, 2004, 104 (09) :3723-3750

[10] Phthalocyanines: old dyes, new materials. Putting color in nanotechnology [J].

de la Torre, Gema ;

Claessens, Christian G. ;

Torres, Tomas .

CHEMICAL COMMUNICATIONS, 2007, (20) :2000-2015

← 1 2 3 4 →