Novel Cu(I) dinuclear complexes containing μ2-η2,η2-type benzoquinone ligand

被引：23

作者：

Masaoka, S

Akiyama, G

Horike, S

Kitagawa, S ^{[1
]}

Ida, T

Endo, K

机构：

[1] Kyoto Univ, Dept Synthet Chem & Biol Chem, Grad Sch Engn, Sakyo Ku, Kyoto 6068501, Japan

[2] Kanazawa Univ, Dept Chem, Fac Sci, Kanazawa, Ishikawa 9201192, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 05期

关键词：

D O I：

10.1021/ja029023z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel Cu(I) complexes containing a μ2-η2,η2-type benzoquinone ligand have been synthesized and crystallographycally characterized. These complexes are synthesized by the redox reaction of a copper-quinonoid pair and may indicate a significant intermediate in the Cu-BQ catalytic system. Moreover, this study is regarded as one of the good examples in the Cu(I)-olefin family of enhanced π-back-donation. Copyright © 2003 American Chemical Society.

引用

页码：1152 / 1153

页数：2

共 15 条

[11] Studies on charge distribution and valence tautomerism in transition metal complexes of catecholate and semiquinonate ligands [J].