Single intermedium-temperature SOFC prepared by glycine-nitrate process

被引:56
作者
Ji, Y [1 ]
Liu, J
He, TM
Cong, LG
Wang, JX
Su, WH
机构
[1] Jilin Univ, Dept Phys, Changchun 130023, Peoples R China
[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China
[3] Acad Sinica, Int Ctr Mat Phys, Shenyang 110015, Peoples R China
[4] Harbin Inst Technol, Ctr Condensed Matter Sci & Technol, Harbin 150001, Peoples R China
关键词
electrode materials; composite materials; fuel cells; electrochemical reactions;
D O I
10.1016/S0925-8388(02)01198-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A combustion synthesis method, the glycine-nitrate process, was used to prepare all nano-size materials used in a single intermedium-temperature solid-oxide fuel cell (IT-SOFC). Samaria-doped ceria (CeO2)(0.9)(SmO1.5)(0.1) (SDC) was used as electrolyte, La0.6Sr0.4Fe0.8Co0.2O3 (LSCF) with 50 wt% SDC was selected as the cathode, and a SDC-Ni composite powder was used as the anode. In this study, the performance of the SOFC was obtained from 250 to 750 degreesC. The highest open circuit voltage was about 0.95 V at 450 degreesC and the maximum power density of 0.104 W cm(-2) and a short circuit current density of 500 mA cm(-2) of the cell were achieved at 750 degreesC. The initial cell performance showed that, with a proper choice of synthesis process and technology, a SOFC using CeO2-based materials as electrolyte operating at IT-temperature is a realistic goal. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:257 / 262
页数:6
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