Factors influencing coordination versus oxidative addition of C-H bonds to molybdenum and tungsten: Structural and spectroscopic evidence that the calixarene framework promotes C-H bond activation

被引：8

作者：

Buccella, Daniela

Tanski, Joseph M.

Parkin, Gerard ^{[1
]}

机构：

[1] Columbia Univ, Dept Chem, New York, NY 10027 USA

[2] Vassar Coll, Poughkeepsie, NY 12604 USA

来源：

ORGANOMETALLICS | 2007年 / 26卷 / 14期

关键词：

D O I：

10.1021/om700279c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mo(PMe3)(6) and W(PMe3)(4)(eta(2)-CH2PMe2)H react with the diphenol CH2((ArOH)-O-Me2)(2) (Ar-Me2 = C6H2Me2) to yield [kappa(2),eta(2)-CH2((ArO)-O-Me2)(2)]M(PMe3)(3)H-2 (M = Mo, W), which possess agostic M-H-C interactions. NMR spectroscopic studies provide evidence that the tungsten compound is in facile equilibrium with the metalated trihydride [kappa(3)-CH((ArO)-O-Me2)(2)]W(PMe3)(3)H-3.

引用

页码：3275 / 3278

页数：4

共 16 条

[11]

Melnick JG, 2006, DALTON T, P4207, DOI 10.1039/b607916d

[12] SYNTHETIC, STRUCTURAL, AND MECHANISTIC STUDIES OF THE C-H BOND ACTIVATION OF PHENOLS BY W(PME3)6 AND W(PME3)4(ETA-2-CH2PME2)H [J].