Periodic Array of Polyelectrolyte-Gated Organic Transistors from Electrospun Poly(3-hexylthiophene) Nanofibers

被引:184
作者
Lee, Sung W. [2 ]
Lee, Hyun J. [3 ]
Choi, Ji H. [2 ]
Koh, Won G. [3 ]
Myoung, Jae M. [2 ]
Hur, Jae H. [4 ]
Park, Jong J. [4 ]
Cho, Jeong H. [1 ]
Jeong, Unyong [2 ]
机构
[1] Soongsil Univ, Dept Organ Mat & Fiber Engn, Seoul, South Korea
[2] Yonsei Univ, Dept Mat Sci & Engn, Seoul 120749, South Korea
[3] Yonsei Univ, Dept Chem & Biomol Engn, Seoul 120749, South Korea
[4] Samsung Adv Inst Technol, Yongin 446712, Gyeonggi Do, South Korea
基金
新加坡国家研究基金会;
关键词
Organic field effect transistors; polyelectrolyte; P3HT nanofiber; electrospinning; ion gel; FIELD-EFFECT TRANSISTORS; THIN-FILM TRANSISTORS; LOW-VOLTAGE; EFFECT MOBILITY; FABRICATION; DIELECTRICS; TRANSPORT;
D O I
10.1021/nl903722z
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
High-performance organic field-effect. transistors (OFETs) based on polyelectrolyte gate dielectric and electrospun poly(3-hexylthiophene) (P3HT) nanofibers were fabricated oil a flexible polymer substrate. The use of UV-crosslinked hydrogel including ionic liquids for the insulating layer enabled fast and large-area fabrication of transistor arrays. The P3HT nanofibers were directly deposited on the methacrylated polymer substrate. During UV irradiation through a patterned mask, the methacrylate groups formed covalent bonds with the patterned polyelectrolyte dielectric layer, which provides mechanical stability to the devices. The OFETs operate at voltages of less than 2 V. The average field-effect mobility and on/off ratio were similar to 2 cm(2)/(Vs) and 10(5), respectively.
引用
收藏
页码:347 / 351
页数:5
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