Ultrasonic effects on electroorganic processes Part 14. Indirect electroreduction of benzyl chlorides with anthracene redox-mediatory system

被引：9

作者：

Atobe, M ^{[1
]}

Kado, Y ^{[1
]}

Nonaka, T ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Elect Chem, Midori Ku, Yokohama, Kanagawa 2268502, Japan

来源：

ULTRASONICS SONOCHEMISTRY | 2000年 / 7卷 / 03期

关键词：

cavitation; indirect electrolysis; sonoelectrochemistry;

D O I：

10.1016/S1350-4177(99)00036-X

中图分类号：

O42 [声学];

学科分类号：

070206 ; 082403 ;

摘要：

Ultrasonic effects were observed in the indirect electroreduction of benzyl chlorides with a radical anion mediator electrogenerated from anthracene. Both the current efficiency for the toluenes formed and the current density (reaction rate) at a working electrode were significantly increased in potential-controlled electrolysis under ultrasonic irradiation (20 kHz). These effects are important from a practical aspect and are rationalized as being due to mass transport promotion caused by ultrasonic cavitation. Although the efficiency could be also increased in the direct electroreduction in the absence of the mediator under irradiation, the current density was only slightly increased. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：97 / 102

页数：6