A potent greenhouse gas identified in the atmosphere:: SF5CF3

被引:126
作者
Sturges, WT [1 ]
Wallington, TJ
Hurley, MD
Shine, KP
Sihra, K
Engel, A
Oram, DE
Penkett, SA
Mulvaney, R
Brenninkmeijer, CAM
机构
[1] Univ E Anglia, Sch Environm Sci, Norwich NR4 7TJ, Norfolk, England
[2] Ford Motor Co, Dearborn, MI 48121 USA
[3] Univ Reading, Dept Meteorol, Reading RG6 6BB, Berks, England
[4] Univ Frankfurt, Inst Meteorol & Geophys, D-60325 Frankfurt, Germany
[5] British Antarctic Survey, NERC, Cambridge CB3 0ET, England
[6] Max Planck Inst Chem, Div Atmospher Chem, D-55060 Mainz, Germany
关键词
D O I
10.1126/science.289.5479.611
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
We detected a compound previously unreported in the atmosphere, trifluoromethyl sulfur pentafluoride (SF5CF3). Measurements of its infrared absorption cross section show SF5CF3 to have a radiative forcing of 0.57 watt per square meter per parts per billion. This is the largest radiative forcing, on a per molecule basis, of any gas found in the atmosphere to date. Antarctic firn measurements show it to have grown from near zero in the late 1960s to about 0.12 part per trillion in 1999. It is presently growing by about 0.008 part per trillion per year, or 6% per year. Stratospheric profiles of SF5CF3 suggest that it is long-Lived in the atmosphere (on the order of 1000 years).
引用
收藏
页码:611 / 613
页数:3
相关论文
共 17 条
[1]  
[Anonymous], 1996, Intergovernmental Panel on Climate Change
[2]   Radiative forcing of climate change by CFC-11 and possible CFC-replacements [J].
Christidis, N ;
Hurley, MD ;
Pinnock, S ;
Shine, KP ;
Wallington, TJ .
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1997, 102 (D16) :19597-19609
[3]  
DUDHIA A, 1997, POMAOXFGS0003 ESA U
[4]   Partitioning between chlorine reservoir species deduced from observations in the arctic winter stratosphere [J].
Engel, A ;
Schmidt, U ;
Stachnik, RA .
JOURNAL OF ATMOSPHERIC CHEMISTRY, 1997, 27 (02) :107-126
[5]   Determination of gas diffusivity in polar firn: Comparison between experimental measurements and inverse modeling [J].
Fabre, A ;
Barnola, JM ;
Arnaud, L ;
Chappellaz, J .
GEOPHYSICAL RESEARCH LETTERS, 2000, 27 (04) :557-560
[6]   Southern Hemispheric halon trends (1978-1998) and global halon emissions [J].
Fraser, PJ ;
Oram, DE ;
Reeves, CE ;
Penkett, SA ;
McCulloch, A .
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1999, 104 (D13) :15985-15999
[7]   Greenhouse gas radiative forcing: Effects of averaging and inhomogeneities in trace gas distribution [J].
Freckleton, RS ;
Highwood, EJ ;
Shine, KP ;
Wild, O ;
Law, KS ;
Sanderson, MG .
QUARTERLY JOURNAL OF THE ROYAL METEOROLOGICAL SOCIETY, 1998, 124 (550) :2099-2127
[8]   A NEW METHOD FOR PREDICTION OF BINARY GAS-PHASE DIFFUSION COEFFECIENTS [J].
FULLER, EN ;
SCHETTLE, PD ;
GIDDINGS, JC .
INDUSTRIAL AND ENGINEERING CHEMISTRY, 1966, 58 (05) :19-+
[9]  
GOODWIN JWL, 1999, UK EMISSIONS AIR POL
[10]   GLOBAL INCREASE OF SF6 OBSERVED IN THE ATMOSPHERE [J].
MAISS, M ;
LEVIN, I .
GEOPHYSICAL RESEARCH LETTERS, 1994, 21 (07) :569-572