Organic-inorganic hybrid solids:: control of perhalometallate solid state structures

被引:145
作者
Gillon, AL
Lewis, GR
Orpen, AG
Rotter, S
Starbuck, J
Wang, XM
Rodríguez-Martín, Y
Ruiz-Pérez, C
机构
[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
[2] Univ La Laguna, Dept Fis Fundamental 2, San Cristobal la Laguna 38204, Spain
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 21期
关键词
D O I
10.1039/b005036i
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
MX . . . HN+ hydrogen bond synthons have been exploited in preparation of crystalline salts [4,4'-H(2)bipy][MX4] [X=Cl, M=Pd, Pt, Co, Zn, Hg, Mn, Cd and Pb; X=Br, M=Pd, Co, Zn and Mn]. In these salts three structural forms for the halometallate species are observed: mononuclear square planar (M=Pd, Pt) or tetrahedral (M=Co, Zn, Hg) and polymeric cis edge-sharing octahedral (M=Mn, Cd, Pb). These correspond to three structural motifs which form the basis of the crystal structures formed in their [4,4'-H(2)bipy](2+) salts: ribbon polymer (M=Pt, Pd); herring-bone packing of cyclic dimers (M=Co, Zn, Hg); layer cross-linked polymers [{MX4}(n)](2n-) (M=Mn, Cd, Pb). The factors controlling the structures adopted, the hierarchy of intermolecular interactions present in these crystals and the principles that may be inferred and exploited further are considered.
引用
收藏
页码:3897 / 3905
页数:9
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