Organic-inorganic hybrid solids:: control of perhalometallate solid state structures

被引:145
作者
Gillon, AL
Lewis, GR
Orpen, AG
Rotter, S
Starbuck, J
Wang, XM
Rodríguez-Martín, Y
Ruiz-Pérez, C
机构
[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
[2] Univ La Laguna, Dept Fis Fundamental 2, San Cristobal la Laguna 38204, Spain
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2000年 / 21期
关键词
D O I
10.1039/b005036i
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
MX . . . HN+ hydrogen bond synthons have been exploited in preparation of crystalline salts [4,4'-H(2)bipy][MX4] [X=Cl, M=Pd, Pt, Co, Zn, Hg, Mn, Cd and Pb; X=Br, M=Pd, Co, Zn and Mn]. In these salts three structural forms for the halometallate species are observed: mononuclear square planar (M=Pd, Pt) or tetrahedral (M=Co, Zn, Hg) and polymeric cis edge-sharing octahedral (M=Mn, Cd, Pb). These correspond to three structural motifs which form the basis of the crystal structures formed in their [4,4'-H(2)bipy](2+) salts: ribbon polymer (M=Pt, Pd); herring-bone packing of cyclic dimers (M=Co, Zn, Hg); layer cross-linked polymers [{MX4}(n)](2n-) (M=Mn, Cd, Pb). The factors controlling the structures adopted, the hierarchy of intermolecular interactions present in these crystals and the principles that may be inferred and exploited further are considered.
引用
收藏
页码:3897 / 3905
页数:9
相关论文
共 55 条
  • [41] Exploration of a simple universal route to the myriad of open-framework metal phosphates
    Rao, CNR
    Natarajan, S
    Neeraj, S
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (12) : 2810 - 2817
  • [42] Rivas JCM, 1999, COORDIN CHEM REV, V183, P43
  • [43] Rivas JCM, 1998, NEW J CHEM, V22, P1315
  • [44] Rivas JCM, 1998, INORG CHEM, V37, P4756
  • [45] ROBSON R, 1992, ACS SYM SER, V499, P256
  • [46] 1,3-propanediammonium tetrachloromercurate
    Spengler, R
    Zouari, R
    Zimmermann, H
    Salah, AB
    Burzlaff, H
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1998, 54 : 1628 - 1631
  • [47] SPENGLER R, 1988, ACTA CRYSTALLOGR C, V54
  • [48] Secondary bonding as a potential design element for crystal engineering
    Starbuck, J
    Norman, NC
    Orpen, AG
    [J]. NEW JOURNAL OF CHEMISTRY, 1999, 23 (10) : 969 - 972
  • [49] Nitrile functionalised pendant-arm derivatives of [9]aneN3 as new multidentate ligands for inorganic crystal engineering ([9]aneN3 1,4,7-triazacyclononane)
    Tei, L
    Lippolis, V
    Blake, AJ
    Cooke, PA
    Schröder, M
    [J]. CHEMICAL COMMUNICATIONS, 1998, (23) : 2633 - 2634
  • [50] CRYSTAL-STRUCTURE AND MAGNETISM OF 4,4'-BIPYRIDYLIUM DI-MU-BROMOTETRABROMODICUPRATE(II)
    TOSIK, A
    BUKOWSKASTRZYZEWSKA, M
    MROZINSKI, J
    [J]. JOURNAL OF COORDINATION CHEMISTRY, 1990, 21 (03) : 253 - 261