Solid state hydrolysis/polycondensation of alkoxysilane: Access to crystal-like silicon-based hybrid materials

被引：44

作者：

Muramatsu, H ^{[1
]}

Corriu, R ^{[1
]}

Boury, B ^{[1
]}

机构：

[1] Univ Montpellier 2, Lab Chim Mol & Org Solide, UMR 5637, F-34090 Montpellier, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 04期

关键词：

D O I：

10.1021/ja020975e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Transformation of a crystallized molecular solid to a periodically organized covalent extended solid was obtained by a solvent-free process of an organosilane. Hydrolysis and further polycondensation occur in the solid state; in addition this route leads to crystal-like silicon-based hybrid materials with a higher periodicity than material prepared by sol-gel process. Copyright © 2003 American Chemical Society.

引用

页码：854 / 855

页数：2

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