Solid state hydrolysis/polycondensation of alkoxysilane: Access to crystal-like silicon-based hybrid materials

被引：44

作者：

Muramatsu, H ^{[1
]}

Corriu, R ^{[1
]}

Boury, B ^{[1
]}

机构：

[1] Univ Montpellier 2, Lab Chim Mol & Org Solide, UMR 5637, F-34090 Montpellier, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 04期

关键词：

D O I：

10.1021/ja020975e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Transformation of a crystallized molecular solid to a periodically organized covalent extended solid was obtained by a solvent-free process of an organosilane. Hydrolysis and further polycondensation occur in the solid state; in addition this route leads to crystal-like silicon-based hybrid materials with a higher periodicity than material prepared by sol-gel process. Copyright © 2003 American Chemical Society.

引用

页码：854 / 855

页数：2

共 23 条

[11]

2-S

[12]

Förster S, 2002, ANGEW CHEM INT EDIT, V41, P689

[13] THERMAL-BEHAVIOR OF AMIDE SUBSTITUTED DIACETYLENES [J].

KATO, J ;

NAKAMURA, K ;

YAMAZAKI, S ;

TOKUSHIGE, K ;

AMANO, T .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1989, 27 (06) :1853-1862

[14]

LIVAGE J, 1998, CHEM ADV MAT OVERVIE

[15] Self-organized hybrid silica with long-range ordered lamellar structure [J].

Moreau, JJE ;

Vellutini, L ;

Man, MWC ;

Bied, C ;

Bantignies, JL ;

Dieudonné, P ;

Sauvajol, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (32) :7957-7958

[16] New hybrid organic-inorganic solids with helical morphology via H-bond mediated sol-gel hydrolysis of silyl derivatives of chiral (R,R)- or (S,S)-diureidocyclohexane [J].

Moreau, JJE ;

Vellutini, L ;

Man, MWC ;

Bied, C .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (07) :1509-1510

[17] 4-CENTER TYPE PHOTOPOLYMERIZATION IN CRYSTALLINE STATE .5. X-RAY CRYSTALLOGRAPHIC STUDY OF POLYMERIZATION OF 2,5-DISTYRYLPYRAZINE [J].

NAKANISHI, H ;

HASEGAWA, M ;

SASADA, Y .

JOURNAL OF POLYMER SCIENCE PART A-2-POLYMER PHYSICS, 1972, 10 (08) :1537-+

[18] PHOTOCHEMICAL-REACTIONS OF ORGANIC-CRYSTALS [J].

RAMAMURTHY, V ;

VENKATESAN, K .

CHEMICAL REVIEWS, 1987, 87 (02) :433-481

[19]

Sanchez C, 2001, CHEM MATER, V13, P3061, DOI 10.1021/cm01106le

[20]

Scherrer G.W, 1990, DRYING SOL GEL SCI

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