Steric and electronic factors influencing recognition by a simple, charge neutral norbornene based anion receptor

被引:61
作者
Lowe, Adam J. [1 ]
Dyson, Gail A. [1 ]
Pfeffer, Frederick M. [1 ]
机构
[1] Deakin Univ, Sch Life & Environm Sci, Geelong, Vic 3217, Australia
关键词
COLORIMETRIC CHEMOSENSORS; N-H; THIOUREA; SENSORS; DERIVATIVES; CHEMISTRY; TRANSPORT; DESIGN; PYROPHOSPHATE; MOLECULES;
D O I
10.1039/b703626b
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Based on H-1 NMR studies, subtle electronic factors rather than pre-organisation dictate the binding stoichiometry of the new, norbornene based, anion hosts 1 and 2 with acetate, however, the binding of dihydrogenphosphate appears to be based solely on steric constraints.
引用
收藏
页码:1343 / 1346
页数:4
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