Synthesis of methylene- and methine-bridged oligopyridines

被引:36
作者
Dyker, G
Muth, O
机构
[1] Ruhr Univ Bochum, Fak Chem, D-44780 Bochum, Germany
[2] Univ Duisburg Gesamthsch, Fak Nat Wissensch, D-47048 Duisburg, Germany
关键词
multidentate ligands; lithiation; nucleophilic substitution; nitrogen heterocycles;
D O I
10.1002/ejoc.200400435
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A variety of methylene- and methine-bridged oligopyridines are conveniently accessible through stepwise nucleophilic aromatic substitution with fluoro-substituted pyridines. The yields achieved are regularly above 90%. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004).
引用
收藏
页码:4319 / 4322
页数:4
相关论文
共 38 条
[31]   Suprasupermolecules with novel properties: Metallodendrimers [J].
Newkome, GR ;
He, EF ;
Moorefield, CN .
CHEMICAL REVIEWS, 1999, 99 (07) :1689-1746
[32]   THE USE OF ORGANOLITHIUM COMPOUNDS TO EFFECT THE ALKYLATION OF 2-PICOLINE AND 4-PICOLINE [J].
OSUCH, C ;
LEVINE, R .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (08) :1723-1725
[33]  
Polson MIJ, 2002, EUR J INORG CHEM, P2549
[34]   New self-assembled structural motifs in coordination chemistry [J].
Swiegers, Gerhard F. ;
Malefetse, Tshepo J. .
Chemical Reviews, 2000, 100 (09) :3483-3537
[35]   Coordination chemistry of tripyridinedimethane [J].
Vedernikov, AN ;
Huffman, JC ;
Caulton, KG .
INORGANIC CHEMISTRY, 2002, 41 (24) :6244-6248
[36]   Lanthanide(III) complexes of tripodal N-donor ligands:: Structural models for the species involved in solvent extraction of actinides(III) [J].
Wietzke, R ;
Mazzanti, M ;
Latour, JM ;
Pécaut, J ;
Cordier, PY ;
Madic, C .
INORGANIC CHEMISTRY, 1998, 37 (26) :6690-6697
[37]   Catalytic and selective conversion of glycine into serine by the reaction with formaldehyde in a neutral aqueous solution [J].
Yashiro, M .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2002, 75 (06) :1383-1384
[38]   SYNTHESIS AND METAL-BINDING PROPERTIES OF POLYBIPYRIDINE LIGANDS DERIVED FROM ACYCLIC AND MACROCYCLIC POLYAMINES [J].
ZIESSEL, R ;
LEHN, JM .
HELVETICA CHIMICA ACTA, 1990, 73 (05) :1149-1162