In search of molecular rectifiers.: The donor-σ-acceptor system derived from triptycenequinone and tetrathiafulvalene

被引：59

作者：

Scheib, S ^{[1
]}

Cava, MP ^{[1
]}

Baldwin, JW ^{[1
]}

Metzger, RM ^{[1
]}

机构：

[1] Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1998年 / 63卷 / 04期

关键词：

D O I：

10.1021/jo9717393

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Several donor-sigma-acceptor compounds (8, 9, 13, and 14) have been synthesized that contain a sterically hindered quinone tethered by a tetramethylene chain to a substituted tetrathiafulvalene. Compounds 13 and 14 show a dramatic increase (approximate to 450 mV) in the oxidation potential of the dipyrrolo-TTF unit, suggestive of considerable electron withdrawal through the sigma-bridge. Monolayers of 9 and 14 are metastable at the air-water interface.

引用

页码：1198 / 1204

页数：7

共 16 条

[11] ELECTRON EXCHANGE POLYMERS .10. A GENERAL METHOD FOR THE PREPARATION OF PHENOLIC POLYSTYRENES [J].