Phthalocyanines - Versatile components of molecular conductors

被引：258

作者：

Inabe, T ^{[1
]}

Tajima, H

机构：

[1] Hokkaido Univ, Grad Sch Sci, Div Chem, Sapporo, Hokkaido 0600810, Japan

[2] Univ Tokyo, Inst Solid State Phys, Kashiwa, Chiba 2778581, Japan

来源：

CHEMICAL REVIEWS | 2004年 / 104卷 / 11期

关键词：

D O I：

10.1021/cr030649x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pc-based conductors with clearly defined structures were evaluated. When planar Pc complexes were the components, only the 1D system was obtained. However, these complexes were found to exhibit properties as a 1D system. Furthermore, it was observed that the electronic properties at low temperature were severely affected by the defects or impurities in the crystal due to their highly one-dimensional electronic structure. These results provide evidence that most of the M(Pc)Xy one-dimensional partially oxidized salts do not show metal-to-insulator transitions with definite lattice distortions down to very low temperature.

引用

页码：5503 / 5533

页数：31

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