Larger Spontaneous Polarization Ferroelectric Inorganic-Organic Hybrids: [PbI3]∞ Chains Directed Organic Cations Aggregation to Kagome-Shaped Tubular Architecture

被引：107

作者：

Zhao, Hai-Rong ^{[1
,2
]}

Li, Dong-Ping ^{[3
,4
]}

Ren, Xiao-Ming ^{[1
,2
]}

Song, You ^{[3
,4
]}

Jin, Wan-Qin ^{[2
]}

机构：

[1] Nanjing Univ Technol, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Peoples R China

[2] Nanjing Univ Technol, Coll Sci, Nanjing 210009, Peoples R China

[3] Nanjing Univ, State Key Lab, Nanjing 210093, Peoples R China

[4] Nanjing Univ, Inst Coordinat Chem, Nanjing 210093, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 01期

关键词：

OPTICAL NONLINEARITY; MOLECULAR-CRYSTALS; TRANSITIONS; COMPLEXES; FRAMEWORK; COMPOUND; IODIDE;

D O I：

10.1021/ja907562m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Four isostructural inorganic-organic hybrid ferroelectric Compounds, assembled from achiral 3-R-benzylidene-1-aminopyridiniums (R = NO2, Br, Cl, or F for 1-4, respectively) and [PbI3](-) anions with the chiral Kagome-shaped tubular aggregating architecture, show larger spontaneous polarizations.

引用

页码：18 / +

页数：4

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