Hybrid solar cells with ordered TiO2 nanostructures and MEH-PPV

被引:67
作者
Kim, Seok-Soon [1 ]
Jo, Jang [1 ]
Chun, Chaemin [1 ]
Hong, Jae-Chul [1 ]
Kim, Dong-Yu [1 ]
机构
[1] GIST, Heeger Ctr Adv Mat, Dept Mat Sci & Engn, Kwangju 500712, South Korea
关键词
hybrid solar cells; TiO2; nanostructure; surface relief gratings;
D O I
10.1016/j.jphotochem.2006.12.037
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
For use in hybrid solar cells consisting of TiO2 and poly[2-methoxy, 5-(2'-ethyl-hexyloxy)-1,4-phenylenevinylene] (MEH-PPV), a TiO2 nanostructure which has periodic hexagonal hole arrays was fabricated using surface relief gratings on azobenzene-functionalized polymer films as a template in the sol-gel reaction of a Ti-precusor. The ordered bulk heterojunction solar cells, prepared with the TiO2 nanostructure and MEH-PPV, have a higher power conversion efficiency of 0.21% compared to bilayer and random bulk heterojunction solar cells fabricated with thin-dense TiO2 films and randomly networked TiO2 nanoparticles, respectively, under one sun with air mass 1.5 global illumination. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:364 / 370
页数:7
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