Thiol-Ene Click Chemistry

被引：3487

作者：

Hoyle, Charles E. ^{[2
]}

Bowman, Christopher N. ^{[1
]}

机构：

[1] Univ Colorado, Dept Chem & Biochem Engn, Boulder, CO 80309 USA

[2] Univ So Mississippi, Sch Polymers & High Performance Mat, Hattiesburg, MS 39406 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 09期

基金：

美国国家卫生研究院; 美国国家科学基金会;

关键词：

click chemistry; Michael additions; polymerization; synthesis design; thiol-ene reaction; DISPERSED LIQUID-CRYSTAL; METHACRYLATE TERNARY-SYSTEMS; SELECTIVE CONJUGATE ADDITION; FREE-RADICAL ADDITION; POLYMERIZATION KINETICS; MECHANICAL-PROPERTIES; SURFACE MODIFICATION; DIBLOCK COPOLYMERS; NETWORK FORMATION; BLOCK-COPOLYMERS;

D O I：

10.1002/anie.200903924

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

"Chemical Equation Presented" Click and easy: The radical thiol-ene reaction (see scheme) fulfills all the criteria for being a click reaction, and it has a unique potential for applications in polymer science and molecular synthesis. Particular advantages are simplicity, high yields and conversions, high reaction rates, and the possibility of photoinitiation. © 2010 Wlley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1540 / 1573

页数：34

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