A simple and novel eco-friendly process for the one-pot synthesis of dithiocarbamates from amines, carbon disulfide, and epoxides

被引：57

作者：

Azizi, Najmedin

Pourhasan, Bahram

Aryanasab, Fezzeh

Saidi, Mohammad R.

机构：

[1] Sharif Univ Technol, Dept Chem, Tehran 11365, Iran

[2] Chem & Chem Engn Res Ctr Iran, Tehran 11365, Iran

来源：

SYNLETT | 2007年 / 08期

关键词：

atom economy; dithiocarbamate; epoxide; amine; solvent-free;

D O I：

10.1055/s-2007-977450

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An environmentally benign, highly efficient, and simple protocol for the synthesis of various structurally divergent dithiocarbamate derivatives in one-pot reaction of amines, carbon disulfide, and epoxides, without using any solvent and catalyst at room temperature, is presented. This new procedure has the advantages of higher yield, lower cost, reduced environmental impact, and simple work-up procedure.

引用

收藏

页码：1239 / 1242

页数：4

相关论文

共 51 条

[11] Magnesium bistrifluoromethanesulfonimide as a new and efficient acylation catalyst [J].

Chakraborti, Asit K. ;

Shivani .

JOURNAL OF ORGANIC CHEMISTRY, 2006, 71 (15) :5785-5788

[12] STEREOSPECIFIC TOTAL SYNTHESIS OF A SLOW REACTING SUBSTANCE OF ANAPHYLAXIS, LEUKOTRIENE C-1 [J].

COREY, EJ ;

CLARK, DA ;

GOTO, G ;

MARFAT, A ;

MIOSKOWSKI, C ;

SAMUELSSON, B ;

HAMMARSTROM, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (04) :1436-1439

[13] An efficient one-pot synthesis of 2-hydroxyalkyl dithiocarbamates [J].

Cui, JL ;

Ge, ZM ;

Cheng, TM ;

Li, RT .

SYNTHETIC COMMUNICATIONS, 2003, 33 (12) :1969-1976

[14] Synthetic approaches towards 2-iminothiazolidines: an overview [J].

D'hooghe, M ;

De Kimpe, N .

TETRAHEDRON, 2006, 62 (04) :513-535

[15]

Dunn A. D., 1989, CARBON DISULPHIDE OR, P226

[16] InCl3-catalyzed regio- and stereloselective thiolysis of α,β-epoxycarboxylic acids in water [J].

Fringuelli, F ;

Pizzo, F ;

Tortoioli, S ;

Vaccaro, L .

ORGANIC LETTERS, 2005, 7 (20) :4411-4414

[17] Easy and environmentally friendly uncatalyzed synthesis of β-hydroxy arylsulfides by thiolysis of 1,2-epoxides in water [J].

Fringuelli, F ;

Pizzo, F ;

Tortoioli, S ;

Vaccaro, L .

GREEN CHEMISTRY, 2003, 5 (04) :436-440

[18]

Fringuelli F, 2002, ADV SYNTH CATAL, V344, P379, DOI 10.1002/1615-4169(200206)344:3/4<379::AID-ADSC379>3.0.CO

[19]

2-4

[20] A practical procedure for the large-scale preparation of methyl (2R,3S)-3-(4-methoxyphenyl)glycidate, a key intermediate for diltiazem [J].

Furutani, T ;

Imashiro, R ;

Hatsuda, M ;

Seki, M .

JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (13) :4599-4601

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