A NbO-type metal-organic framework derived from a polyyne-coupled di-isophthalate linker formed in situ

被引：136

作者：

Zhao, Dan ^{[1
]}

Yuan, Daqiang ^{[1
]}

Yakovenko, Andrey ^{[1
]}

Zhou, Hong-Cai ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 23期

基金：

美国国家科学基金会;

关键词：

HIGH H-2 ADSORPTION; HYDROGEN STORAGE; HIGH-CAPACITY; PORE-SIZE; COORDINATION POLYMERS; METHANE STORAGE; DESIGN; CARBON; FUNCTIONALIZATION; SORPTION;

D O I：

10.1039/c002767g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A NbO-type metal-organic framework, PCN-46, was constructed based on a polyyne-coupled di-isophthalate linker formed in situ. Its lasting porosity was confirmed by N(2) adsorption isotherm, and its H(2), CH(4) and CO(2) adsorption capacity was examined at 77 K and 298 K over a wide pressure range (0-110 bar).

引用

收藏

页码：4196 / 4198

页数：3

相关论文

共 36 条

[1]

BURCHELL T, 2000, 200020012205 SAE

[2] High H2 adsorption in a microporous metal-organic framework with open metal sites [J].

Chen, BL ;

Ockwig, NW ;

Millward, AR ;

Contreras, DS ;

Yaghi, OM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (30) :4745-4749

[3] Solvothermal in situ metal/ligand reactions: A new bridge between coordination chemistry and organic synthetic chemistry [J].

Chen, Xiao-Ming ;

Tong, Ming-Liang .

ACCOUNTS OF CHEMICAL RESEARCH, 2007, 40 (02) :162-170

[4] Industrial applications of metal-organic frameworks [J].

Czaja, Alexander U. ;

Trukhan, Natalia ;

Mueller, Ulrich .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1284-1293

[5] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].

Eddaoudi, M ;

Kim, J ;

Rosi, N ;

Vodak, D ;

Wachter, J ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2002, 295 (5554) :469-472

[6] Hybrid porous solids:: past, present, future [J].

Ferey, Gerard .

CHEMICAL SOCIETY REVIEWS, 2008, 37 (01) :191-214

[7] Advancesn in CO2 capture technology -: The US Department of Energy's Carbon Sequestration Program [J].

Figueroa, Jose D. ;

Fout, Timothy ;

Plasynski, Sean ;

McIlvried, Howard ;

Srivastava, Rameshwar D. .

INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL, 2008, 2 (01) :9-20

[8] Effects of surface area, free volume, and heat of adsorption on hydrogen uptake in metal-organic frameworks [J].

Frost, Houston ;

Dueren, Tina ;

Snurr, Randall Q. .

JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (19) :9565-9570

[9]

Glaser C., 1869, Chem. Ber, V2, P422, DOI [10.1002/cber.186900201183, DOI 10.1002/CBER.186900201183]

[10] High H2 storage of hexagonal metal-organic frameworks from first-principles-based grand canonical Monte Carlo simulations [J].

Han, Sang Soo ;

Goddard, William A., III .

JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (35) :13431-13436

← 1 2 3 4 →