A NbO-type metal-organic framework derived from a polyyne-coupled di-isophthalate linker formed in situ

被引：136

作者：

Zhao, Dan ^{[1
]}

Yuan, Daqiang ^{[1
]}

Yakovenko, Andrey ^{[1
]}

Zhou, Hong-Cai ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 23期

基金：

美国国家科学基金会;

关键词：

HIGH H-2 ADSORPTION; HYDROGEN STORAGE; HIGH-CAPACITY; PORE-SIZE; COORDINATION POLYMERS; METHANE STORAGE; DESIGN; CARBON; FUNCTIONALIZATION; SORPTION;

D O I：

10.1039/c002767g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A NbO-type metal-organic framework, PCN-46, was constructed based on a polyyne-coupled di-isophthalate linker formed in situ. Its lasting porosity was confirmed by N(2) adsorption isotherm, and its H(2), CH(4) and CO(2) adsorption capacity was examined at 77 K and 298 K over a wide pressure range (0-110 bar).

引用

收藏

页码：4196 / 4198

页数：3

相关论文

共 36 条

[11] METHOD FOR THE CALCULATION OF EFFECTIVE PORE-SIZE DISTRIBUTION IN MOLECULAR-SIEVE CARBON [J].

HORVATH, G ;

KAWAZOE, K .

JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1983, 16 (06) :470-475

[12] A new MOF-505 analog exhibiting high acetylene storage [J].

Hu, Yunxia ;

Xiang, Shengchang ;

Zhang, Wenwei ;

Zhang, Zhuxiu ;

Wang, Lei ;

Bai, Junfeng ;

Chen, Banglin .

CHEMICAL COMMUNICATIONS, 2009, (48) :7551-7553

[13] Functional porous coordination polymers [J].

Kitagawa, S ;

Kitaura, R ;

Noro, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (18) :2334-2375

[14] A comparison of the H2 sorption capacities of isostructural metal-organic frameworks with and without accessible metal sites:: [{Zn2(abtc)(dMf)2}3] and [{Cu2(abtc)(dMf)2}3] versus [{Cu2(abtc)}3] [J].

Lee, Yong-Gon ;

Moon, Hoi Ri ;

Cheon, Young Eun ;

Suh, Myunghyun Paik .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (40) :7741-7745

[15] High H2 adsorption by coordination-framework materials [J].

Lin, Xiang ;

Jia, Junhua ;

Zhao, Xuebo ;

Thomas, K. Mark ;

Blake, Alexander J. ;

Walker, Gavin S. ;

Champness, Neil R. ;

Hubberstey, Peter ;

Schroeder, Martin .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (44) :7358-7364

[16] High Capacity Hydrogen Adsorption in Cu(II) Tetracarboxylate Framework Materials: The Role of Pore Size, Ligand Functionalization, and Exposed Metal Sites [J].

Lin, Xiang ;

Telepeni, Irvin ;

Blake, Alexander J. ;

Dailly, Anne ;

Brown, Craig M. ;

Simmons, Jason M. ;

Zoppi, Marco ;

Walker, Gavin S. ;

Thomas, K. Mark ;

Mays, Timothy J. ;

Hubberstey, Peter ;

Champness, Neil R. ;

Schroeder, Martin .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (06) :2159-2171

[17] High uptakes of CO2 and CH4 in mesoporous metal-organic frameworks MIL-100 and MIL-101 [J].

Llewellyn, Philip L. ;

Bourrelly, Sandrine ;

Serre, Christian ;

Vimont, Alexandre ;

Daturi, Marco ;

Hamon, Lornig ;

De Weireld, Guy ;

Chang, Jong-San ;

Hong, Do-Young ;

Hwang, Young Kyu ;

Jhung, Sung Hwa ;

Ferey, Gerard .

LANGMUIR, 2008, 24 (14) :7245-7250

[18] Metal-organic framework from an anthracene derivative containing nanoscopic cages exhibiting high methane uptake [J].

Ma, Shengqian ;

Sun, Daofeng ;

Simmons, Jason M. ;

Collier, Christopher D. ;

Yuan, Daqiang ;

Zhou, Hong-Cai .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (03) :1012-1016

[19] Gas storage in porous metal-organic frameworks for clean energy applications [J].

Ma, Shengqian ;

Zhou, Hong-Cai .

CHEMICAL COMMUNICATIONS, 2010, 46 (01) :44-53

[20] Porous Metal-Organic Frameworks Based on an Anthracene Derivative: Syntheses, Structure Analysis, and Hydrogen Sorption Studies [J].

Ma, Shengqian ;

Simmons, Jason M. ;

Sun, Daofeng ;

Yuan, Daqiang ;

Zhou, Hong-Cai .

INORGANIC CHEMISTRY, 2009, 48 (12) :5263-5268

← 1 2 3 4 →