Metal-organic framework from an anthracene derivative containing nanoscopic cages exhibiting high methane uptake

被引:784
作者
Ma, Shengqian [1 ]
Sun, Daofeng [1 ]
Simmons, Jason M. [2 ,3 ]
Collier, Christopher D. [1 ]
Yuan, Daqiang [1 ]
Zhou, Hong-Cai [1 ]
机构
[1] Miami Univ, Dept Chem & Biochem, Oxford, OH 45056 USA
[2] Natl Inst Stand & Technol, NIST Ctr Neutron Res, Gaithersburg, MD 20899 USA
[3] Univ Penn, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA
基金
美国国家科学基金会;
关键词
D O I
10.1021/ja0771639
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A microporous metal-organic framework, PCN-14, based on an anthracene derivative, 5,5'(9,1 0-anthracenediyl)di-isophthalate (H(4)adip), was synthesized under solvothermal reaction conditions. X-ray single crystal analysis revealed that PCN-14 consists of nanoscopic cages suitable for gas storage. N-2-adsorption studies of PCN-14 at 77 K reveal a Langmuir surface area of 2176 m(2)/g and a pore volume of 0.87 cm(3)/g. Methane adsorption studies at 290 K and 35 bar show that PCN-14 exhibits an absolute methane-adsorption capacity of 230 v/v, 28% higher than the DOE target (180 v/v) for methane storage.
引用
收藏
页码:1012 / 1016
页数:5
相关论文
共 52 条
  • [1] [Anonymous], 2001, SAINT VERS 6 22
  • [2] Different adsorption behaviors of methane and carbon dioxide in the isotypic nanoporous metal terephthalates MIL-53 and MIL-47
    Bourrelly, S
    Llewellyn, PL
    Serre, C
    Millange, F
    Loiseau, T
    Férey, G
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (39) : 13519 - 13521
  • [3] Design, chirality, and flexibility in nanoporous molecule-based materials
    Bradshaw, D
    Claridge, JB
    Cussen, EJ
    Prior, TJ
    Rosseinsky, MJ
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) : 273 - 282
  • [4] BURCHELL T, 2000, SAE TECH PAP SER
  • [5] A route to high surface area, porosity and inclusion of large molecules in crystals
    Chae, HK
    Siberio-Pérez, DY
    Kim, J
    Go, Y
    Eddaoudi, M
    Matzger, AJ
    O'Keeffe, M
    Yaghi, OM
    [J]. NATURE, 2004, 427 (6974) : 523 - 527
  • [6] Rationally designed micropores within a metal-organic framework for selective sorption of gas molecules
    Chen, Banglin
    Ma, Shengqian
    Zapata, Fatima
    Fronczek, Frank R.
    Lobkovsky, Emil B.
    Zhou, Hong-Cai
    [J]. INORGANIC CHEMISTRY, 2007, 46 (04) : 1233 - 1236
  • [7] Hydrogen adsorption in an interpenetrated dynamic metal-organic framework
    Chen, Banglin
    Ma, Shengqian
    Zapata, Fatima
    Lobkovsky, Emil B.
    Yang, Jun
    [J]. INORGANIC CHEMISTRY, 2006, 45 (15) : 5718 - 5720
  • [8] High H2 adsorption in a microporous metal-organic framework with open metal sites
    Chen, BL
    Ockwig, NW
    Millward, AR
    Contreras, DS
    Yaghi, OM
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (30) : 4745 - 4749
  • [9] Hydrogen storage in metal-organic frameworks
    Collins, David J.
    Zhou, Hong-Cai
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (30) : 3154 - 3160
  • [10] Hydrogen storage in a microporous metal-organic framework with exposed Mn2+ coordination sites
    Dinca, Mircea
    Dailly, Anne
    Liu, Yun
    Brown, Craig M.
    Neumann, Dan. A.
    Long, Jeffrey R.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (51) : 16876 - 16883