High H2 adsorption by coordination-framework materials

被引：706

作者：

Lin, Xiang

Jia, Junhua

Zhao, Xuebo

Thomas, K. Mark

Blake, Alexander J.

Walker, Gavin S.

Champness, Neil R.

Hubberstey, Peter

Schroeder, Martin

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

[2] Univ Nottingham, Sch Mech Mat & Mfg Engn, Nottingham NG7 2RD, England

[3] Newcastle Univ, Dept Chem, No Carbon Res Labs, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 44期

关键词：

adsorption; copper; hydrogen storage; metal-organic frameworks; microporous materials;

D O I：

10.1002/anie.200601991

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

First-class accommodation: A series of coordination frameworks with different pore sizes (see structure of one; Cu blue, C gray, H white, O red) are prepared from CuII ions and carboxylate ligands of various lengths. Comparison of their sorption properties reveals that smaller pores allow higher densities of adsorbed H2, whereas larger pores allow higher maximum H2 storage capacities. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

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收藏

页码：7358 / 7364

页数：7

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