Homoleptic zinc amides: Transition to monomeric molecules

被引：25

作者：

Schumann, H ^{[1
]}

Gottfriedsen, J ^{[1
]}

Girgsdies, F ^{[1
]}

机构：

[1] Tech Univ Berlin, Inst Anorgan & Analyt Chem, D-10623 Berlin, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1997年 / 623卷 / 12期

关键词：

zinc amides; monomeric zinc amides; dimeric zinc amides; X-ray structures;

D O I：

10.1002/zaac.19976231210

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Zinc chloride reacts with the lithium salts of the bulky secondary amines HN(i-Bu)(2) and HN(t-Bu)(2) to form the corresponding homoleptic zinc compounds (Zn[N(i-Bu)(2)](2))(2) (1) and Zn[N(t-Bu)(2)](2) (2). The NMR spectroscopic and mass spectrometric results as well as the molecular weight determinations and X-ray diffraction data are consistent with a dimeric structure of 1 and a monomeric structure of 2 in the gas phase,in solution and in the solid state.

引用

页码：1881 / 1884

页数：4

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