Hydrothermal Route for Cutting Graphene Sheets into Blue-Luminescent Graphene Quantum Dots

被引:2576
作者
Pan, Dengyu [1 ]
Zhang, Jingchun [2 ]
Li, Zhen [2 ]
Wu, Minghong [2 ]
机构
[1] Shanghai Univ, Inst Nanochem & Nanobiol, Shanghai 201800, Peoples R China
[2] Shanghai Univ, Shanghai Appl Radiat Inst, Shanghai 201800, Peoples R China
关键词
CARBON NANOTUBES;
D O I
10.1002/adma.200902825
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Water-soluble graphene quantum dots (GQDs, ca. 10 nm in diameter) that exhibit bright blue photoluminescence (PL) are prepared by hydrothermal (chemical) cutting of oxidized graphene sheets (see figure). The mechanisms of the cutting and luminescence are discussed. his discovery of PL of GQDs may extend T the range of application of graphene-based materials to optoelectronics and biological labeling.
引用
收藏
页码:734 / +
页数:6
相关论文
共 30 条
[1]   Stable carbenes [J].
Bourissou, D ;
Guerret, O ;
Gabbaï, FP ;
Bertrand, G .
CHEMICAL REVIEWS, 2000, 100 (01) :39-91
[2]   Surface functionalized carbogenic quantum dots [J].
Bourlinos, Athanasios B. ;
Stassinopoulos, Andreas ;
Anglos, Demetrios ;
Zboril, Radek ;
Karakassides, Michael ;
Giannelis, Emmanuel P. .
SMALL, 2008, 4 (04) :455-458
[3]  
Choucair M, 2009, NAT NANOTECHNOL, V4, P30, DOI [10.1038/nnano.2008.365, 10.1038/NNANO.2008.365]
[4]   The rise of graphene [J].
Geim, A. K. ;
Novoselov, K. S. .
NATURE MATERIALS, 2007, 6 (03) :183-191
[5]   Energy band-gap engineering of graphene nanoribbons [J].
Han, Melinda Y. ;
Oezyilmaz, Barbaros ;
Zhang, Yuanbo ;
Kim, Philip .
PHYSICAL REVIEW LETTERS, 2007, 98 (20)
[6]   TRIMETHYLENE AND ADDITION OF METHYLENE TO ETHYLENE [J].
HOFFMANN, R .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (06) :1475-&
[7]   Brightly Fluorescent Single-Walled Carbon Nanotubes via an Oxygen-Excluding Surfactant Organization [J].
Ju, Sang-Yong ;
Kopcha, William P. ;
Papadimitrakopoulos, Fotios .
SCIENCE, 2009, 323 (5919) :1319-1323
[8]   Longitudinal unzipping of carbon nanotubes to form graphene nanoribbons [J].
Kosynkin, Dmitry V. ;
Higginbotham, Amanda L. ;
Sinitskii, Alexander ;
Lomeda, Jay R. ;
Dimiev, Ayrat ;
Price, B. Katherine ;
Tour, James M. .
NATURE, 2009, 458 (7240) :872-U5
[9]   Processable aqueous dispersions of graphene nanosheets [J].
Li, Dan ;
Mueller, Marc B. ;
Gilje, Scott ;
Kaner, Richard B. ;
Wallace, Gordon G. .
NATURE NANOTECHNOLOGY, 2008, 3 (02) :101-105
[10]   Oxygen-driven unzipping of graphitic materials [J].
Li, JL ;
Kudin, KN ;
McAllister, MJ ;
Prud'homme, RK ;
Aksay, IA ;
Car, R .
PHYSICAL REVIEW LETTERS, 2006, 96 (17)