Quantitative formation of the intermediate of alkene insertion in the copolymerization of p-methylstyrene and carbon monoxide catalyzed by [(PriDAB)Pd(Me)(NCMe)]+BAr4-

被引:44
作者
Carfagna, C [1 ]
Formica, M [1 ]
Gatti, G [1 ]
Musco, A [1 ]
Pierleoni, A [1 ]
机构
[1] Univ Urbino, Ist Sci Chim, I-61029 Urbino, PS, Italy
关键词
D O I
10.1039/a801158c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The intermediate after the first CO and p-methylstyrene insertion in the chain growth process of the copolymerization of these monomers has been quantitatively obtained from [(Pr(i)DAB)Pd(Me)(NCMe)](+)[{3,5-(CF3)(2)C6H3}(4)B](-) in CHCl3 at 20 degrees C.
引用
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页码:1113 / 1114
页数:2
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