Organocatalytic Asymmetric Synthesis of Organophosphorus Compounds

被引:164
作者
Albrecht, Lukasz [1 ,2 ]
Albrecht, Anna [2 ]
Krawczyk, Henryk [2 ]
Jorgensen, Karl Anker [1 ]
机构
[1] Aarhus Univ, Dept Chem, Ctr Catalysis, DK-8000 Aarhus C, Denmark
[2] Tech Univ Lodz, Inst Organ Chem, Dept Chem, PL-90924 Lodz, Poland
基金
新加坡国家研究基金会;
关键词
asymmetric synthesis; organocatalysis; organophosphorus compounds; phoshonates; phosphines; PHOSPHONIC ACID-DERIVATIVES; CATALYZED ENANTIOSELECTIVE HYDROPHOSPHONYLATION; WITTIG OLEFINATION REACTION; ALPHA-HYDROXY PHOSPHONATES; MICHAEL ADDITION; CONJUGATE ADDITION; CARBONYL-COMPOUNDS; ALPHA; BETA-UNSATURATED ALDEHYDES; PHOSPHORORGANISCHE VERBINDUNGEN; STEREOSELECTIVE-SYNTHESIS;
D O I
10.1002/chem.200902634
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
240 Years have passed since the discovery of elemental phosphorus. During that time organophosphorus chemistry has emerged as an interesting and exciting field of research. Recently organophosphorus chemistry has been raised to a new level. Organophosphorus compounds have found applications in asymmetric organocatalysis for the synthesis of optically active compounds of synthetic or biological importance. The aim of this review article is to present recent contributions to this developing field of chemistry and to point out synthetic advantages of methodologies developed so far.
引用
收藏
页码:28 / 48
页数:21
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