Microwave-initiated living free radical polymerization: rapid formation of custom Rasta resins

被引：37

作者：

Wisnoski, DD ^{[1
]}

Leister, WH ^{[1
]}

Strauss, KA ^{[1
]}

Zhao, ZJ ^{[1
]}

Lindsley, CW ^{[1
]}

机构：

[1] Merck Res Labs, Technol Enabled Synth Grp, Dept Med Chem, W Point, PA 19486 USA

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 23期

关键词：

D O I：

10.1016/S0040-4039(03)00951-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Microwave heating of high-loading TEMPO-methyl resin with functionalized styrenyl monomers in a SmithSynthesizer(TM) affords larger resin beads (>500 mum) via living free radical polymerization. Novel, high-loading Rasta resins (>5.5 mmol/g) are obtained similar to150 times faster than with conventional heating. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：4321 / 4325

页数：5

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