Controlled incorporation of water molecules into carboxy hydrogen-bond networks:: A designed approach

被引：18

作者：

Pérez, C

Rodríguez, ML

Foces-Foces, C

Pérez-Hernández, N

Pérez, R

Martín, JD

机构：

[1] CSIC, Inst Quim Fis Rocasolano, Dept Cristalog, E-28006 Madrid, Spain

[2] Univ La Laguna, CSIC, Inst Bioorgan, E-38206 Tenerife, Spain

[3] CSIC, Inst Invest Quim, Seville 41092, Spain

来源：

ORGANIC LETTERS | 2003年 / 5卷 / 05期

关键词：

D O I：

10.1021/ol027332o

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] The incorporation of water molecules into the hydrogen-bonded pattern of condensed organic materials implies an unfavorable entropic tradeoff resulting from water ordering. Here we show for a family of diacids of general structure (+/-)-1 that extended chains of anhydrous or hydrated structures can be prepared by controlling the steric factors that lead to the closest packing of individual components.

引用

页码：641 / 644

页数：4

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