Reactive applications of cyclic alkylene carbonates

被引：683

作者：

Clements, JH ^{[1
]}

机构：

[1] Huntsman Petrochem Corp, Austin, TX 78752 USA

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2003年 / 42卷 / 04期

关键词：

D O I：

10.1021/ie020678i

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The synthesis and use of cyclic alkylene carbonates as reactive intermediates first appeared in the literature more than 50 years ago. However, the range of their usefulness in industrial applications has only been fully realized in the past decade. In this article, numerous reactive applications of the cyclic alkylene carbonates, specifically the five-membered cyclics, are discussed. In addition, utilization of the chemistry presented in this review for the preparation of industrially useful monomers, polymers, surfactants, plasticizers, cross-linking agents, curing agents, and solvents, to name a few, is also discussed.

引用

页码：663 / 674

页数：12

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[21] Single-site β-diiminate zinc catalysts for the alternating copolymerization of CO2 and epoxides:: Catalyst synthesis and unprecedented polymerization activity [J].