We describe a new application of iodobenzenediacetate (IBDA), which is able to oxidize thiocyanate anion to the corresponding radical. Subsequent addition to nucleophilic olefins leads to dithiocyanate derivatives. The radical addition to olefins is more effective when performing the thiocyanation reaction in presence of Mg(ClO4)(2) or TEMPO.
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页码:1889 / 1892
页数:4
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VARVOGLIS A, 1992, ORGANIC CHEM POLYCOO, P108