Radical additions to olefins in the presence of iodobenzenediacetate: An easy route to alkyl dithiocyanates

被引：38

作者：

DeMico, A

Margarita, R

Mariani, A

Piancatelli, G

机构：

[1] UNIV ROMA LA SAPIENZA,DIPARTIMENTO CHIM,I-00185 ROME,ITALY

[2] CNR,CTR STUDIO CHIM SOSTANZE ORGAN NAT,I-00185 ROME,ITALY

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 11期

关键词：

D O I：

10.1016/0040-4039(96)00144-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We describe a new application of iodobenzenediacetate (IBDA), which is able to oxidize thiocyanate anion to the corresponding radical. Subsequent addition to nucleophilic olefins leads to dithiocyanate derivatives. The radical addition to olefins is more effective when performing the thiocyanation reaction in presence of Mg(ClO4)(2) or TEMPO.

引用

页码：1889 / 1892

页数：4