Morphosynthesis of rhombododecahedral silver cages by self-assembly coupled with precursor crystal templating

被引:174
作者
Yang, JH [1 ]
Qi, LM [1 ]
Lu, CH [1 ]
Ma, JM [1 ]
Cheng, HM [1 ]
机构
[1] Peking Univ, Coll Chem, State Key Lab Struct Chem Unstable & Stable Speci, Beijing 100871, Peoples R China
关键词
D O I
10.1002/anie.200461859
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Through the reduction of micrometer-sized silver phosphate crystals with a perfect rhombododecahedral shape by a reaction/diffusion process to hierarchical, rhombododecahedral silver cages (see picture): The controlled self-assembly of silver particles around the precursor crystal surfaces leads to the formation of morphology-preserved single- or double-walled silver cages constructed from different building units.
引用
收藏
页码:598 / 603
页数:6
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