Synthesis of Donor-Acceptor Multiblock Copolymers Incorporating Fullerene Backbone Repeat Units

被引:51
作者
Hiorns, Roger C. [1 ,2 ,3 ]
Cloulet, Eric [2 ,3 ]
Ibarboure, Emmanuel [2 ,3 ]
Khoukh, Abdel
Bejbouji, Habiba [4 ]
Vignau, Laurence [4 ]
Cramail, Henri [3 ]
机构
[1] Univ Pau & Pays Adour, CNRS, IPREM, EPCP,UMR 5254, F-64053 Pau, France
[2] CNRS, Lab Chim Polymeres Organ, F-33607 Pessac, France
[3] Univ Bordeaux, Lab Chim Polymeres Organ, ENSCBP, F-33607 Pessac, France
[4] Univ Bordeaux, Lab Integrat Mat Syst, CNRS, UMR 5218,ENSCBP, F-33607 Pessac, France
关键词
INTERNAL QUANTUM EFFICIENCY; BLOCK-COPOLYMER; MOLECULAR-WEIGHT; SOLAR-CELLS; REGIOREGULAR POLY(3-HEXYLTHIOPHENE); PLASTIC ELECTRONICS; DIBLOCK COPOLYMERS; CHARGE SEPARATION; SELF-ORGANIZATION; POLYMERS;
D O I
10.1021/ma100694y
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The synthesis of the first example ()la block copolymer based on a polymer using fullerene as a backbone repeat subunit is demonstrated A facile route incorporating the electron acceptor and high fullerene content polymer, poly{(1,4-fullerene)-alt-[1,4-dimethylene-2,5-bis(cyclohexylmethylether)phenylene]} (PFDP), with the archetypal electron donor, poly(3-hexylthiophene) (P3HT), into a multiblock copolymer (M BC) structure is presented alpha,omega-Bromomethyl-PFDP was prepared by atom-transfer radical addition polymerization (ATRAP) and then reacted with alpha,omega-phenol-P3HT via a Williamson condensation to yield the MBCs The lengths of the electron-acceptor and donor polymer blocks could be selected so that the resulting solid state domains were of a size appropriate to organic solar cells Also 11 was found that the MBCs gave a wide range of macro-structures, from micelles to well-defined wires, depending on the preparation conditions
引用
收藏
页码:6033 / 6044
页数:12
相关论文
共 118 条
[41]   The synthesis of organometallic rod-coil block copolymers from polysilanes [J].
Hiorns, Roger C. ;
Holder, Simon J. .
POLYMER INTERNATIONAL, 2009, 58 (03) :323-329
[42]   About supramolecular assemblies of π-conjugated systems [J].
Hoeben, FJM ;
Jonkheijm, P ;
Meijer, EW ;
Schenning, APHJ .
CHEMICAL REVIEWS, 2005, 105 (04) :1491-1546
[43]   The Gilch polymerisation towards OC1C10-PPV:: indications for a radical mechanism [J].
Hontis, L ;
Vrindts, V ;
Lutsen, L ;
Vanderzande, D ;
Gelan, J .
POLYMER, 2001, 42 (13) :5793-5796
[44]   Regio- and diastereo-controlled synthesis of bis(formylmethano)[60]fullerenes and their application to the formation of [60]fullerene pearl-necklace polyimines [J].
Ito, H ;
Ishida, Y ;
Saigo, K .
TETRAHEDRON LETTERS, 2006, 47 (18) :3095-3098
[45]   Polymer electronic materials: a review of charge transport [J].
Jaiswal, Manu ;
Menon, Reghu .
POLYMER INTERNATIONAL, 2006, 55 (12) :1371-1384
[46]   Facile synthesis of end-functionalized regioregular poly(3-alkylthiophene)s via modified Grignard metathesis reaction [J].
Jeffries-El, M ;
Sauvé, G ;
McCullough, RD .
MACROMOLECULES, 2005, 38 (25) :10346-10352
[47]   Synthesis and spectroscopic and electrochemical characterization of di- and tetrasubstituted C60 derivatives [J].
Kadish, KM ;
Gao, X ;
Van Caemelbecke, E ;
Hirasaka, T ;
Suenobu, T ;
Fukuzumi, S .
JOURNAL OF PHYSICAL CHEMISTRY A, 1998, 102 (22) :3898-3906
[48]   Effect of addition pattern on the electrochemical and spectroscopic properties of neutral and reduced 1,2-and 1,4-(C6H5CH2)2C60 isomers [J].
Kadish, KM ;
Gao, X ;
Van Caemelbecke, E ;
Suenobu, T ;
Fukuzumi, S .
JOURNAL OF PHYSICAL CHEMISTRY A, 2000, 104 (17) :3878-3883
[49]  
KALLITSIS J, 2006, SEMICONDUCTING POLYM, V1, pCH2
[50]   Synthesis of a Bifunctional Initiator for Controlled Kumada Catalyst-Transfer Polycondensation/Nitroxide-Mediated Polymerization and Preparation of Poly(3-hexylthiophene)-Polystyrene Block Copolymer Therefrom [J].
Kaul, Elisabeth ;
Senkovskyy, Volodymyr ;
Tkachov, Roman ;
Bocharova, Vera ;
Komber, Hartmut ;
Stamm, Manfred ;
Kiriy, Anton .
MACROMOLECULES, 2010, 43 (01) :77-81