Potassium hydride as nucleophile:: A practical method for cleavage and functional modification of Cr(CO)3-Ar-SiMe3 bonds

被引:10
作者
Mandal, SK [1 ]
Sarkar, A [1 ]
机构
[1] Natl Chem Lab, Div Organ Chem Synth, Pune 411008, Maharashtra, India
关键词
D O I
10.1021/jo971856y
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Potassium hydride reacts with Cr(CO)(3)-aryltrimethylsilanes at roam temperature to generate stabilized aryl anions which can further react with electrophiles.
引用
收藏
页码:1901 / 1905
页数:5
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