Porous polyaniline exhibits highly enhanced electrochemical capacitance performance

被引:82
作者
Liu, Jingliang [1 ]
Zhou, Mengqi [1 ]
Fan, Li-Zhen [1 ,2 ]
Li, Ping [1 ]
Qu, Xuanhui [1 ]
机构
[1] Univ Sci & Technol Beijing, Beijing Key Lab Adv Powder Met, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
[2] Shenzhen Capchem Technol Co Ltd, Shenzhen 518118, Peoples R China
关键词
Porous polyaniline; Conducting polymer; Supercapacitor; Capacitance; SUPERCAPACITORS; CARBON; COMPOSITES; OXIDE;
D O I
10.1016/j.electacta.2010.05.030
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Porous polyaniline (PANI) is prepared by using sodium dodecylsulfate as a soft template and ammonium persulfate as an oxidant. Transmission electron microscopy and nitrogen adsorption-desorption isotherms suggest the existence of both macro/mesopores and micropores, and the specific surface area of 211 m(2) g(-1). As a result of its porous structure, the porous PANI exhibits highly enhanced utilization ratio during the charge-discharge cycles. This porous PANI also displays high cycle stability and rate capability. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:5819 / 5822
页数:4
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