Porous polyaniline exhibits highly enhanced electrochemical capacitance performance

被引:82
作者
Liu, Jingliang [1 ]
Zhou, Mengqi [1 ]
Fan, Li-Zhen [1 ,2 ]
Li, Ping [1 ]
Qu, Xuanhui [1 ]
机构
[1] Univ Sci & Technol Beijing, Beijing Key Lab Adv Powder Met, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
[2] Shenzhen Capchem Technol Co Ltd, Shenzhen 518118, Peoples R China
关键词
Porous polyaniline; Conducting polymer; Supercapacitor; Capacitance; SUPERCAPACITORS; CARBON; COMPOSITES; OXIDE;
D O I
10.1016/j.electacta.2010.05.030
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Porous polyaniline (PANI) is prepared by using sodium dodecylsulfate as a soft template and ammonium persulfate as an oxidant. Transmission electron microscopy and nitrogen adsorption-desorption isotherms suggest the existence of both macro/mesopores and micropores, and the specific surface area of 211 m(2) g(-1). As a result of its porous structure, the porous PANI exhibits highly enhanced utilization ratio during the charge-discharge cycles. This porous PANI also displays high cycle stability and rate capability. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:5819 / 5822
页数:4
相关论文
共 18 条
[11]   Effects of electrochemical-deposition method and microstructure on the capacitive characteristics of nano-sized manganese oxide [J].
Shinomiya, Takuya ;
Gupta, Vinay ;
Miura, Norio .
ELECTROCHIMICA ACTA, 2006, 51 (21) :4412-4419
[12]   Materials for electrochemical capacitors [J].
Simon, Patrice ;
Gogotsi, Yury .
NATURE MATERIALS, 2008, 7 (11) :845-854
[13]   3D aperiodic hierarchical porous graphitic carbon material for high-rate electrochemical capacitive energy storage [J].
Wang, Da-Wei ;
Li, Feng ;
Liu, Min ;
Lu, Gao Qing ;
Cheng, Hui-Ming .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (02) :373-376
[14]   Ordered whiskerlike polyaniline grown on the surface of mesoporous carbon and its electrochemical capacitance performance [J].
Wang, Yong-Gang ;
Li, Hui-Qiao ;
Xia, Yong-Yao .
ADVANCED MATERIALS, 2006, 18 (19) :2619-+
[15]   Nanocrystalline oxide supercapacitors [J].
Wu, NL .
MATERIALS CHEMISTRY AND PHYSICS, 2002, 75 (1-3) :6-11
[16]   Rate capability of lithium intercalation into nano-porous graphitized carbons [J].
Yamada, Hirotoshi ;
Watanabe, Yuko ;
Moriguchi, Isamu ;
Kudo, Tetsuichi .
SOLID STATE IONICS, 2008, 179 (27-32) :1706-1709
[17]   High power battery electrodes using nanoporous V2O5/carbon composites [J].
Yamada, Hirotoshi ;
Tagawa, Kazuki ;
Komatsu, Masaharu ;
Moriguchi, Isamu ;
Kudo, Tetsuichi .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (23) :8397-8402
[18]   Carbon nanotube arrays and their composites for electrochemical capacitors and lithium-ion batteries [J].
Zhang, Hao ;
Cao, Gaoping ;
Yang, Yusheng .
ENERGY & ENVIRONMENTAL SCIENCE, 2009, 2 (09) :932-943