The coordination chemistry of 4-substituted 3,5-di(2-pyridyl)-4H-1,2,4-triazoles and related ligands

被引：377

作者：

Klingele, MH ^{[1
]}

Brooker, S ^{[1
]}

机构：

[1] Univ Otago, Dept Chem, Dunedin, New Zealand

来源：

COORDINATION CHEMISTRY REVIEWS | 2003年 / 241卷 / 1-2期

关键词：

1,2,4-triazole; 1,3,4-oxadiazole; 1,3,4-thiadiazole; bridging ligand; binding mode; spin crossover;

D O I：

10.1016/S0010-8545(03)00049-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The coordination chemistry of 4-substituted 3,5-di(2-pyridyl)-4H-1,2,4-triazoles, as well as of the related ligands 2,5-di(2-pyridyl)1,3,4-oxadiazole and 2,5-di(2-pyridyl)-1,3,4-thiadiazole, is comprehensively reviewed. Literature surveys of the known 4-substituted 3,5-di(2-pyridyl)-4H-1,2,4-triazoles and their complexes are provided, selected representative examples are presented and the various coordination modes that have been observed in complexes of these potentially dinucleating ligands are discussed. (C) 2003 Elsevier Science B.V. All rights reserved.

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页码：119 / 132

页数：14

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