Mechanistic aspects regarding the formation of metal vinylidenes from alkynes and related reactions

被引：139

作者：

Wakatsuki, Y ^{[1
]}

机构：

[1] RIKEN, OM Chem Tech Co Ltd, Wako, Saitama 3510198, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2004年 / 689卷 / 24期

关键词：

D O I：

10.1016/j.jorganchem.2004.05.052

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review focuses on the tautomerization mechanism between alkynes and vinylidene units taking place in the coordination sphere of transition metal fragments. Reactions of vinylidene complexes as well as catalytic reactions involving a metal-vinylidene intermediate are also reviewed from the mechanistic point of view. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：4092 / 4109

页数：18

共 84 条

[1] VINYLIDENE TRANSITION-METAL COMPLEXES .31. STANNYLALKYNES AS STARTING MATERIALS FOR THE SYNTHESIS OF VINYLIDENE RHODIUM COMPLEXES AND OF HETERODIMETALLIC COMPOUNDS CONTAINING A RH-HG OR RH-SN BOND [J].

BAUM, M ;

MAHR, N ;

WERNER, H .

CHEMISCHE BERICHTE, 1994, 127 (10) :1877-1886

[2] Formation of cationic half-sandwich osmium-vinylidene complexes from [OS(η5-C5H5)(PiPr3)2]+ and terminal alkynes [J].

Baya, M ;

Crochet, P ;

Esteruelas, MA ;

Lopez, AM ;

Modrego, J .

ORGANOMETALLICS, 2001, 20 (20) :4291-4294

[3] PHOTOCHEMICAL ISOMERIZATION OF METAL ETHENE TO METAL VINYL HYDRIDE COMPLEXES - A MATRIX-ISOLATION AND SOLUTION NMR-STUDY [J].

BELL, TW ;

HADDLETON, DM ;

MCCAMLEY, A ;

PARTRIDGE, MG ;

PERUTZ, RN ;

WILLNER, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (25) :9212-9226

[4] METAL HYDRIDE ALKYNYL -] METAL VINYLIDENE REARRANGEMENTS OCCURRING IN BOTH SOLID-STATE AND SOLUTION - ROLE OF THE 1-ALKYNE SUBSTITUENT IN DETERMINING THE RELATIVE STABILITY OF PI-ALKYNE, HYDRIDE ALKYNYL, AND VINYLIDENE FORMS AT COBALT [J].

BIANCHINI, C ;

PERUZZINI, M ;

VACCA, A ;

ZANOBINI, F .

ORGANOMETALLICS, 1991, 10 (10) :3697-3707

[5] The mechanism of the Ru-assisted C-C bond cleavage of terminal alkynes by water [J].

Bianchini, C ;

Casares, JA ;

Peruzzini, M ;

Romerosa, A ;

Zanobini, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (19) :4585-4594

[6] A RU(II) ENYNYL COMPLEX MEDIATES THE CATALYTIC DIMERIZATION OF 1-ALKYNES TO Z-1,4-DISUBSTITUTED ENYNES [J].

BIANCHINI, C ;

PERUZZINI, M ;

ZANOBINI, F ;

FREDIANI, P ;

ALBINATI, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (14) :5453-5454

[7] ACYCLIC CP(CO)2FE DISUBSTITUTED ETA-1-VINYLIDENE-ETA-2-ACETYLENE ISOMERIZATIONS [J].

BLY, RS ;

ZHONG, ZD ;

KANE, C ;

BLY, RK .

ORGANOMETALLICS, 1994, 13 (03) :899-905

[8] ORGANOMETALLIC CHEMISTRY OF VINYLIDENE AND RELATED UNSATURATED CARBENES [J].

BRUCE, MI .

CHEMICAL REVIEWS, 1991, 91 (02) :197-257

[9] CYCLOPENTADIENYL-RUTHENIUM AND CYCLOPENTADIENYL-OSMIUM CHEMISTRY .10. REACTIONS OF VINYLIDENE COMPLEXES WITH ALCOHOLS AND WATER - SYNTHESES OF ALKOXY(ALKYL)CARBENE, ACYL AND ALKYL COMPLEXES [J].

BRUCE, MI ;

SWINCER, AG .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1980, 33 (07) :1471-1483

[10]

BRUCE MI, 1983, ADV ORGANOMET CHEM, V22, P59

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